今有[a]NaH2PO4,[b]KH2PO4和[c]NH4H2PO4三種溶液,其濃度c(NaH2PO4)=c(KH2PO4)=c(NH4H2PO4)=0.10mol/L,則三種溶液的pH的關(guān)系是() [已知H3PO4的pKa1~pKa3分別是2.12、7.20、12.36;pKa(NH4+)=9.26]
A.a=b=c B.a<b<c C.a=b>c D.a=b<c
A.[HPO42-]>[H2PO4-]>[PO43-] B.[HPO42-]>[PO43-]>[H2PO4-] C.[H2PO4-]>[HPO42-]>[H3PO4] D.[H3PO4]>[H2PO4-]>[HPO42-]
pH=7.00的H3AsO4溶液有關(guān)組分平衡濃度的關(guān)系應(yīng)該是() (已知H3AsO4 pKa1=2.20,pKa2=7.00,pKa3=11.50)
A.[H3AsO4]=[H2AsO4-] B.[H2AsO4-]=[HAsO42-] C.[HAsO42-]>[H2AsO4-] D.[H3AsO4]>[HAsO42-]